首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   24846篇
  免费   4014篇
  国内免费   2365篇
化学   17457篇
晶体学   303篇
力学   1512篇
综合类   109篇
数学   2911篇
物理学   8933篇
  2024年   11篇
  2023年   500篇
  2022年   551篇
  2021年   782篇
  2020年   1001篇
  2019年   982篇
  2018年   798篇
  2017年   706篇
  2016年   1168篇
  2015年   1105篇
  2014年   1302篇
  2013年   1753篇
  2012年   2360篇
  2011年   2415篇
  2010年   1583篇
  2009年   1506篇
  2008年   1648篇
  2007年   1511篇
  2006年   1368篇
  2005年   1156篇
  2004年   844篇
  2003年   652篇
  2002年   611篇
  2001年   446篇
  2000年   434篇
  1999年   516篇
  1998年   425篇
  1997年   434篇
  1996年   443篇
  1995年   354篇
  1994年   302篇
  1993年   233篇
  1992年   233篇
  1991年   197篇
  1990年   169篇
  1989年   142篇
  1988年   95篇
  1987年   109篇
  1986年   87篇
  1985年   82篇
  1984年   47篇
  1983年   42篇
  1982年   35篇
  1981年   18篇
  1980年   11篇
  1979年   9篇
  1978年   6篇
  1976年   9篇
  1975年   11篇
  1957年   4篇
排序方式: 共有10000条查询结果,搜索用时 218 毫秒
61.
A simple scheme for single to multi-channel wavelength conversion based on cross-gain modulation of amplified spontaneous emission (ASE) spectrum in semiconductor optical amplifier (SOA) is described. Single to 16-channel wavelength conversion at 10 Gb/s is first demonstrated without any additional probe lights, the modulation information carried by input signal could be converted into arbitrary many channels if only the demultiplexer with enough channels is exploited. Output performance and pattern effects are investigated experimentally.  相似文献   
62.
环境对MgB_2氧化过程中MgO晶须生长形状的影响   总被引:1,自引:0,他引:1  
用扫描电镜研究了在 Mg B2 氧化过程中环境对 Mg O晶须生长形状的影响。仅有 Mg B2 时 ,在 80 0℃左右空气气氛中 ,可生长出纳米尺寸的 Mg O晶须。若把 Mg B2 添加到氧化铝陶瓷基体中 ,则生长成竹节状晶须。Mg O晶须生长形状的差别可能是由于氧浓度以及位错等因素造成的。  相似文献   
63.
We report a nanosecond Nd:YVO_4-pumped optical parametric oscillator (OPO) based on periodically poled LiNbO_3 (PPLN). Tuning is achieved in this experiment by varying the temperature and period of the PPLN. The design of double-pass singly resonant oscillator (DSRO) and confocal cavity enables the OPO threshold to be lowered considerably, resulting in a simple, compact, all-solid-state configuration with the mid-infrared idler powers of up to 466mW at 3.41μm.  相似文献   
64.
Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis. The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate activities for ethylene oligomerization. Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714. This article was submitted by the authors in English.  相似文献   
65.
66.
起源于引力场的Vaidya-Bonner-de Sitter黑洞的量子熵   总被引:8,自引:0,他引:8       下载免费PDF全文
孙鸣超 《物理学报》2003,52(6):1350-1353
利用brick-wall模型研究了引力场对Vaidya-Bonner-de Sitter黑洞熵的量子修正.当黑洞事 件视界不随超前时间变化时,结果与Reissner-Nordstrm-de Sitter黑洞的量子熵完全相 同.  相似文献   
67.
A versatile and efficient sequence was developed for the synthesis of 1-desoxy-Δ8-THC analogues and is demonstrated by the synthesis of sulfonamide analogues with an acetylene group at the C-2 position in the side chain. In this procedure the 1-desoxy-Δ8- THC ring structure is built first and the synthesis of the side chain is then developed.  相似文献   
68.
Ion-exchange resins, especially chelating resins are used for pre-concentration of metal ions in trace analysis as well as for radiochemical separations following neutron activation of a variety of environmental samples. As part of a systematic study of the sorption characteristics of chelating resins, sorption of Zn(II) and Cd(II) by three chelating resins were studied for various acid conditions in nitrate and chloride media. Both Zn(II) and Cd(II) showed similar behavior. Under higher acid conditions, maximum sorption occurred in 3M HCl solutions. Under low acid conditions, the sorption increased with pH. Chelex 100 gave the highest sorption among the three resins. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
69.
The melt mixing technique was used to prepare various polypropylene (PP)‐based (nano)composites. Two commercial organoclays (denoted 20A and 30B) served as the fillers for the PP matrix, and two different maleated (so‐called) compatibilizers (denoted PP‐MA and SMA) were employed as the third component. The results from X‐ray diffraction (XRD) and transmission electron microscope (TEM) experiments revealed that 190 °C was an adequate temperature for preparing the nanocomposites. Nanocomposites were achieved only if specific pairs of organoclay and compatibilizer were simultaneously incorporated in the PP matrix. For example, PP/20A(5 wt %)/PP‐MA(10 wt %) and PP/30B(5 wt %)/SMA(5 wt %) composites exhibited nanoscaled dispersion of 20A or 30B in the PP matrix. Differential scanning calorimetry (DSC) results indicated that the organoclays served as nucleation agents for the PP matrix. Generally, their nucleation effectiveness increased with the addition of compatibilizers. The thermal stability enhancement of PP after adding 20A was confirmed with thermogravimetric analysis (TGA). The enhancement became more evident as a suitable compatibilizer was further added. However, for the 30B‐included composites, thermal stability enhancement was not evident. The dynamic mechanical properties (i.e., storage modulus and loss modulus) of PP increased as the nanocomposites were formed; the properties increment corresponded to the organoclay dispersion status in the matrix. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4139–4150, 2004  相似文献   
70.
A series of polymer electrolytes based on multiarm polymers and lithium salt complexes were characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and impedance measurement. The relationships of conductivity with salt concentration, temperature, and arm numbers are discussed. It is suggested that the star polymer has a higher solvency and ion transfer ability on lithium salts than on linear polymers. The conductivity maximum appeared at a higher salt concentration ([EO]/[Li] = 4). Impedance measurement suggested that the optimum conductivity was 2 × 10?4 s · cm?1. The conductivity increased with temperature and the dependence of ionic conductivity on temperature fits the Arrhenius equation. Among the studied systems, the star polymer with a five arm number performs better than other structures. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4195–4198, 2004  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号